The transfer was announced on Thursday, October, 22 with Agyemang signing a one-year contract.
The 28-year-old has an option to extend the contract to June 2024.
Medeama wrote on Twitter: "All the best in South Africa. Prince of Goals"
He joined the Yellow and Mauves at the beginning of last season following a stellar campaign in the Ghana second-tier with New Edubiase United FC.
He scored 11 goals and provided three assists in 14 games for Medeama.
Agyemang was part of the Black Stars B team that finished second at the 2019 WAFU Cup of Nations in Senegal.
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