The Ghana international replaced Danilo D'Ambrosio after 71 minutes at the San Siro.
But his presence on the pitch could not help the Nerazurri as the Ducali snatched the winner through Federico Dimarco eight minutes later.
Ex-Inter youth product robbed Brozovic in midfield and unleashed a stunning shot from 25 metres that swerved and dipped in off the underside of the bar at the far top corner.
It was his debut Serie A goal.
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