Adiyiah joins Sisaket as a free agent following his exit from Thailand Ligue 1 side Nakhon Ratchasima last year after three seasons at the club.
Sisaket finished 10th in what was a disappointing campaign, ending just eight points above the relegation zone last season.
The former AC Milan player has been brought in to help the team secure qualification to the top flight next season.
Adiyiah, a player who was once preordained as next Ghanaian star after emerging as the Most Valuable Player and top scorer at the 2009 U-20 World Cup which Ghana won, has not had the most enjoyable of club careers.
He has netted just 28 times in 185 appearances in total for nine different clubs in five countries since 2009.
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